Ultrahigh Loading Copper Single Atom Catalyst for Palladium-free Wacker Oxidation

Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by ¹⁸O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts.     

〈111〉晶向冲击加载下单晶铜中纳米孔洞增长的早期动力学行为

利用分子动力学方法模拟计算了单晶铜中纳米孔洞在沿〈111〉晶向冲击加载下增长的早期过程.测量发现不同加载强度下等效孔洞半径随时间近似成线性变化.观测到单孔洞增长的两种位错生长机理：加载强度较低时，只在沿着冲击加载方向的孔洞顶点附近区域有位错的成核和运动；而随着加载强度超过一定阈值，在沿冲击加载和其垂直方向的孔洞顶点区域都观察到位错的成核和运动.在前一种机理作用下，孔洞只沿加载方向增长；在后一种机理作用下，孔洞同时沿加载和垂直于加载方向增长.分析孔洞表面原子的位移历史，发现沿加载及与其垂直方向的孔洞顶点沿径向的速度基本恒定，由此提出了一个孔洞生长模型，可以解释孔洞增长的线性生长规律. 关键词： 纳米孔洞 分子动力学 冲击加载 位错     

介质加载环板慢波结构高频特性研究

 提出了一种适用于环板结构的计算等效相对介电常数的方法，利用变分法导出了介质加载环板慢波结构的色散方程和耦合阻抗表达式。计算结果表明，介质加载能够有效降低环板慢波结构的工作电压。计算结果与CST-MWS的模拟结果吻合良好，说明所提出的计算等效相对介电常数的方法和计算色散方程的方法对环板慢波结构是切实可行的。     

Fractional Brownian Heavy Traffic Approximations of Multiclass Feedforward Queueing Networks

We consider multiclass feedforward queueing networks under first in first out and priority service disciplines driven by long-range dependent arrival and service time processes. We show that in critical loading the normalized workload, queue length and sojourn time processes can converge to a multi-dimensional reflected fractional Brownian motion. This weak heavy traffic approximation is deduced from a deterministic pathwise approximation of the network behavior close to constant critical load in terms of the solution of a Skorokhod problem. Since we model the doubly infinite time interval, our results directly cover the stationary case.AMS subject classification: primary 90B15, secondary 60K25, 68M20     

A novel specimen for investigating the mechanical behavior of elastomers under multiaxial loading conditions

In this paper we describe the design and manufacture of an axial-torsion test specimen, and provide relationships needed when conducting stress-strain characterization experiments with the specimen. The specimen is a short hollow cylinder of rubber bonded between two steel mounting rings, in which simultaneous axial and shear strains are produced via independently controlled axial and twist displacements. We present calculations for the strain-displacement and stress-load relationships, and strain energy density. These relationships have been established and validated via a combination of analytical and experimental techniques, and finite element analysis. We have investigated the extent and effects of strain and stress field non-uniformity in the test specimen. The specimen design is sufficiently simple that a closed-form expression for the strain-displacement relationship has been successfully developed.     

不同温度均匀二半空间接触后产生的辐射场

 应用电磁线路中涨落耗散理论，推导了不同温度均匀二半空间接触后产生辐射场密度的公式。将此公式近似展开后，即得Grover和Urtiew所获得的表示式，不过多了一松弛项，该项如用非富里叶热传导理论推导，也是存在的。该结果和实验结果一致，不过这里的松驰时间可以应用介质性质进行计算。     

电力市场中合同电量与竞争电量交易比例的研究

在单边开放的区域电力市场中,合理的合同电量与竞争电量交易比例是保证电力市场有效运行的一个重要环节。竞争电量所占的比例将主要取决于当前发电公司的市场行为。首先使用BP神经网络对电力需求弹性系数进行了预测,然后以长期电力市场均衡为目标函数,考虑贵州电网发电机组的可用容量与负荷预测的误差,以及贵州输电线路的可靠性诸因素,推导出合同电量与竞争电量交易比例,经过与南方区域电力市场目前运营规则规定的交易比例比较,该比例是合理的,可以规避电力市场价格波动等带来的风险。     

Creep of composites with a porous fibre/matrix interface under variable loading

A micromechanical model of island-type fibre/matrix interface is described and experimental data are represented and analysed. Changes in the interface strength during a cycle loadings and, correspondingly, changes in the creep resistance of a composite due the island-like scheme of the fibre/matrix interface are described.     

甲基百里(香)酚蓝新负载树脂的特 性及应用

本文以金属指示剂甲基百里(香)酚蓝作为鳌合剂制得具有相应鳌合基团的负载树脂.研究了该树脂的某些分析特性及其在富集天然水中微量铜、钻、镍、锌中的应用.     

承受拉-扭组合载荷的薄壁圆筒屈服时产生塑性流动的条件

提出了在无外力作功的情况下，具有Bauschinger效应的弹塑性材料处于屈服状态产生自发的塑性流动时应满足的条件．这个条件不仅与材料的力学性能有关，而且还处决于材料的具体的载荷边界条件和变形．举例说明了承受拉一扭组合的薄壁圆筒中，采用组合强化模型时，产生塑性流动的具体条件．